Materials for Organic Photovoltaic Devices，2009年第8届国际共轭高分子与有机纳米结构光探测大会（6.6-6.10，北京)-中国聚合物网,论文下载

Materials for Organic Photovoltaic Devices

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organic photovoltaic devices

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分子表征

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2009年第8届国际共轭高分子与有机纳米结构光探测大会（6.6-6.10，北京)

简介：

Therehasbeenagreatdealofinterestindevelopingnewmaterialsforthefabricationoflightemittingdiodes(OLEDs).Wehavepreparedarangeofintenselymaterials,whichhavefoundapplicationinbothmonochromaticandwhiteOLEDs.Ourapproachhasinvolvedasystematicstudyofarangeofdifferentmaterials.Wehaveusedasimilarapproachtodevelopmaterialsfororganicphotovoltaicdevices(OPVs).Iwilldiscussthedevelopmentofnewmaterialsasdonors,acceptorsandbufferlayersinOPVs.IwilldiscusstheuseofmetalcomplexesandorganicmaterialsasdonorandacceptormaterialsinorganicsolarcellsandM(-dikenotate)3complexesasbufferlayersinOPVs.WehaveinvestigatedawiderangeofnewandestablishedmaterialstoinvestigatetheconnectionbetweentheOPVopencircuitvoltage(Voc)andtheenergydifferencebetweenthedonorHOMOandacceptorLUMOenergies(EDA).WithincloselyrelatedfamiliesofmaterialsthereisaclearcorrelationbetweenVocandEDA,however,wehavefoundmarkeddifferencesbetweentheVocvaluesformaterialssystemswithverysimilarEDAvalues.IwillpresentamodelthatwehavedevelopedthataccuratelycouplesVocandEDAvalueswithaD/Acouplingterm.ThisapproachgivesusanewpathtodevelophighVocmaterials

作者：

Mark E. Thompson,a M. Dolores Perez,a Cody Schlenker,a Siyi Wang,a Stephen R. Forrestb

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2009-07-20 15:26:17

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