Soft nanocomposite materials with novel organic/inorganic network structures，ICAFPM 2011先进纤维与聚合物材料国际学术会议（2011.8.15~17，上海）-中国聚合物网,论文下载

Soft nanocomposite materials with novel organic/inorganic network structures

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nanocomposite clay hydrogel network mechanical property

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分子表征

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ICAFPM 2011先进纤维与聚合物材料国际学术会议（2011.8.15~17，上海）

简介：

Newtypesofpolymerhydrogelsandpolymernanocomposites,i.e.,nanocompositegels(NCgels)andsoft,polymernanocomposites(M-NCs),withnovelorganic/inorganicnetworkstructureshavebeenfabricated.BothNCgelsandM-NCsweresynthesizedbyin-situfree-radicalpolymerizationinthepresenceofexfoliatedclayplateletsinaqueoussystemsandwereobtainedinvariousformsandsizeswithawiderangeofclaycontents.Here,disk-likeinorganicclaynanoparticlesactasmulti-functionalcrosslinkerstoformnewtypesofnetworksystems.NCgelshaveextraordinaryoptical,mechanical,andswelling/deswellingproperties,aswellasanumberofnewcharacteristicsrelatingtoopticalanisotropy,polymer/claymorphology,biocompatibility,stimuli-sensitivesurfaces,micro-patterning,etc.TheM-NCsalsoexhibitdramaticimprovementsinopticalandmechanicalpropertiesincludingultra-highreversibleextensibilityandwell-definedyieldingbehavior,despitetheirhighclaycontents.Thus,theseriousdisadvantages(intractability,mechanicalfragility,opticalturbidity,poorprocessingability,lowstimulussensitivity,etc.)associatedwiththeconventional,chemically-crosslinkedpolymericmaterialswereovercomeinNCgelsandM-NCs.

作者：

HARAGUCHI Kazutoshi

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2011-10-18 12:57:36

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