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Preparation and characterization of N-methylpolyborosilazane as a precursor of SiBN ceramic fibers  
Preparation and characterization of N-methylpolyborosilazane as a precursor of SiBN ceramic fibers
资料类型: PDF文件
关键词: SiBN  ceramic  fiber  polymer  precursor  polymerization  
资料大小: 3101K
所属学科: 分子表征
来源: ICAFPM 2011先进纤维与聚合物材料国际学术会议(2011.8.15~17,上海)
简介:
SiBNceramicfiberswithexcellentmechanicalandthermalstabilitycanbeobtainedbyN-methylpolyborosilazaneasthepolymerprecursor.Inthispaper,N-methylpolyborosilazanewaspreparedat150℃underdifferenttimeconditionsandexaminedthemeltspinnabilitybyahanddrawingmethod.Theas-obtainedpolymerprecursorswerecharacterizedbyFTIR,NMR,intrinsicviscosityandTGA,andthemorphologyoffiberwasobservedbySEM.Theresultsshowedthatthepolymerprecursorsobtainedatdifferenttimehadnearlythesamestructure,whichwasalargenetworkstructureconsistedofflexiblelinearstructureresponsibleforthegoodmeltspinnabilityandrigidring,andtheirintrinsicviscosityincreasedwiththeincreaseofthemolecularweightexceptingthepresenceofalargedegreeofcrosslinkinginthepolymer.Thepolymerprecursorobtainedat60hdisplayedagoodmeltspinnabilityandrevealedaceramicyieldof60%upto900℃innitrogenatmosphere.
作者: DENG Zhihua, HAN Keqing, ZHANG Jing, PENG Yuqing, WANG Zhenghui, YU Muhuo
上传时间: 2011-10-11 13:19:42
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