A novel hierarchical carbon material based on polyaniline for energy storage，第十届高分子物理国际研讨会（PP’2012)(2012.6.4~8，成都）-中国聚合物网,论文下载

A novel hierarchical carbon material based on polyaniline for energy storage

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分子表征

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第十届高分子物理国际研讨会（PP’2012)(2012.6.4~8，成都）

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Asimportantenergystoragedevices,supercapacitorshaveattractedgreatinterestistsinthepastdecadesduetocombiningtheadvantagesofthehighpowerofdielectriccapacitorswiththehighspecificenergyofrechargeablebatteries,aswellasitsmanypotentialapplications,suchashybridelectricvehicles,uninterruptedpowersupplies,digtalcommunicationdevices,electronicdevices,andotherhigh-powerapparatuses.Asatypicalclassofconductivepolymer,polyaniline(PANI)hasarousedconsiderableattentionoverthelastseveraldecadesbecauseofitssimplepolymerization,chemicalandenvironmentalstability,highelectricalconductivityanditsexcellentelectricalpropertiesbychangingoxidationstatesandprotonationstates.Inrecentyears,PANIisusedasoneoftheattractiveelectrodematerialsforsupercapacitorsduetoitsadvantageouspropertiesincludinglowcostcomparedtonoblemetaloxidesandhighdoping/dedopingrateduringcharge/dischargeprocess.However,theuseofindividualPANIforsupercapacitorelectrodematerialislimitedduetoitspoorcyclestability.WhentheadvantagesofPANIarecombinedwithcarbonmaterials,theresultingnanocompositesprovidesynergisticeffectashighperformanceelectrodematerials[1].Graphene,asingle-atom-thickperfectlytwo-dimensionallatticeofpuresp2-bondedcarbonatomshasrecentlybecomeasensationalmaterialthatdemonstratesanumberofspectacularquantummechanical,optical,andmolecularinteractionphenomena.ThestudyonthenanocompositesofPANIandgraphenehasbeenreportedrecently[2].

作者：

Haosen Fan, Hao Wang, Ning Zhao, Jian Xu

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2012-11-26 14:09:57

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