华南师范大学高进伟教授团队 Small:超分子聚氨酯动态“韧带”增强钙钛矿薄膜机械柔性自愈合能力
2023-10-23 来源:高分子科技
具有重量轻、成本低、易于集成的柔性钙钛矿太阳电池(F-PSCs)有希望补足传统刚性硅太阳电池的应用领域,如建筑一体化光伏、可穿戴和便携式电子设备等。然而,由于钙钛矿薄膜固有的脆性和由此引起的韧性断裂所导致的机械稳定性问题严重限制了F-PSC的光伏性能和寿命。因此,解决F-PSCs的机械稳定性是其实现商业化的基础。
Figure 1. a) Chemical structure of PDMS-PPU. b) Top-view (upper row) and cross-sectional (lower row) SEM images of perovskite films on SnO2/ITO with variable concentration of DSSP-PPU. Scale bars: 500 nm. c) XRD spectra of perovskite films with and without DSSP-PPU. d) HR-TEM of perovskite with DSSP-PPU, the right panels showing the enlarged regions of “1 and 2.” e) GIXRD with different instrumental ψ values (0°–50°) for perovskite with and without DSSP-PPU. f) Linear fit of 2θ-sin2ψ for perovskite with and without DSSP-PPU.
Figure 2. a) Chemical structure of PDMS-PPU. b) Top-view (upper row) and cross-sectional (lower row) SEM images of perovskite films on SnO2/ITO with variable concentration of DSSP-PPU. Scale bars: 500 nm. c) XRD spectra of perovskite films with and without DSSP-PPU. d) HR-TEM of perovskite with DSSP-PPU, the right panels showing the enlarged regions of “1 and 2.” e) GIXRD with different instrumental ψ values (0°–50°) for perovskite with and without DSSP-PPU. f) Linear fit of 2θ-sin2ψ for perovskite with and without DSSP-PPU.
Figure 3. a) Chemical structure of PDMS-PPU. b) Top-view (upper row) and cross-sectional (lower row) SEM images of perovskite films on SnO2/ITO with variable concentration of DSSP-PPU. Scale bars: 500 nm. c) XRD spectra of perovskite films with and without DSSP-PPU. d) HR-TEM of perovskite with DSSP-PPU, the right panels showing the enlarged regions of “1 and 2.” e) GIXRD with different instrumental ψ values (0°–50°) for perovskite with and without DSSP-PPU. f) Linear fit of 2θ-sin2ψ for perovskite with and without DSSP-PPU.
Figure 4. a) Chemical structure of PDMS-PPU. b) Top-view (upper row) and cross-sectional (lower row) SEM images of perovskite films on SnO2/ITO with variable concentration of DSSP-PPU. Scale bars: 500 nm. c) XRD spectra of perovskite films with and without DSSP-PPU. d) HR-TEM of perovskite with DSSP-PPU, the right panels showing the enlarged regions of “1 and 2.” e) GIXRD with different instrumental ψ values (0°–50°) for perovskite with and without DSSP-PPU. f) Linear fit of 2θ-sin2ψ for perovskite with and without DSSP-PPU.
Figure 5. a) Chemical structure of PDMS-PPU. b) Top-view (upper row) and cross-sectional (lower row) SEM images of perovskite films on SnO2/ITO with variable concentration of DSSP-PPU. Scale bars: 500 nm. c) XRD spectra of perovskite films with and without DSSP-PPU. d) HR-TEM of perovskite with DSSP-PPU, the right panels showing the enlarged regions of “1 and 2.” e) GIXRD with different instrumental ψ values (0°–50°) for perovskite with and without DSSP-PPU. f) Linear fit of 2θ-sin2ψ for perovskite with and without DSSP-PPU.
华南师范大学姜月副研究员和高进伟教授为论文的通讯作者,华南师范大学博士研究生杨正池为论文第一作者。感谢国家自然科学基金(No. 62105124,)广东省基础与应用基础研究基金(No. 2022B1515120006, 2022A1515010264)等对本文的资助。相关成果以" Supramolecular polyurethane "Ligaments" Enabling Room-Temperature Self-Healing Flexible Perovskite Solar Cells and Mini-modules"为题发表在期刊《Small》上。
原文链接: https://doi.org/10.1002/smll.202307186
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