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A General Direct C-H Coupling Method for Preparing Conducting Polymers with High Regioregularity
writer:Qiang Zhang, Meijia Chang, Yan Lu*, Yanna Sun, Chenxi Li, Xinlin Yang, Ming Zhang, Yongsheng Chen*
keywords:Oxidative C-H/C-H coupling reaction; Polythiophene, High regioregularity, Head-to tail.
source:期刊
specific source:Macromlolecules, 51 (2), 379-388 (2018). DOI: 10.1021/acs.macromol.7b02390
Issue time:2017年

The Pd-catalysed oxidative C–H/C–H coupling reaction of 3-octylesterthiophene has been used for the first time to synthesize regioregular, head-to-tail coupled poly(3-esterthiophene).