[Chem.Eur.J.]Supramolecular Alternating Polymer from Crown Ether and Pillar[5]arene-Based Double Molecular Recognition for Preparation of Hierarchical Materials
writer:Hui Li, Xiaodong Fan,* Miao Qi, Zhen Yang, Haitao Zhang, and Wei Tian*
keywords:a novel supramolecular alternating polymer,double molecular recognition events,different dimensionalities
source:期刊
specific source:Chem. Eur. J. 2016, 22, 101–105
Issue time:2016年
A novel supramolecular alternating polymer is constructed based on double molecular recognition events of benzo-21-crown-7 with a secondary ammonium salt and of pillar[5]arene with a neutral guest. The resulting polymer is utilized to prepare hierarchical materials with different dimensionalities for the first time. These materials included zero-dimensional spherical aggregates, one-dimensional nanofibers, two-dimensional microstructured films, and three-dimensional ordered glue. This development will be helpful for designing and preparing supramolecular hierarchical materials with different dimensionalities.
全文链接:http://onlinelibrary.wiley.com/doi/10.1002/chem.201504012/abstract