Construction and Biomedical Applications of Macrocycle-Based Supramolecular Topological Polymers
writer:Wenzhuo Chen, Chengfei Liu, Xin Song, Xuedong Xiao, Shuai Qiu, and Wei Tian*
keywords:Construction of Macrocycle-Based Supramolecular Topological Polymers,Biomedical Application of Macrocycle-Based Supramolecular Topological Polymers
source:其他
specific source:Y. Liu et al. (eds.), Handbook of Macrocyclic Supramolecular Assembly,
Issue time:2019年
Supramolecular interactions based on macrocyclic molecules could provide reversible linker for the fabrication of supramolecular systems via noncovalent interactions mainly including electrostatic interactions, π-π stacking, hydrogen bonding, hydrophobic interactions, and host-guest interactions, which have attracted more and more attention arising from their distinctive properties such as good selectivity, high effificiency, and stimuli responsiveness. For decades, a number of macrocyclic host molecules with cavities have been exploited to encapsulate the guests for the construction of novel supramolecular structures and great potential applications in various fifields such as biomedicine, photoelectricity, and catalysis. Among the macrocyclic host molecules, crown ethers, cyclodextrins (CDs), calix[n]arenes (C[n]As), cucurbit[n]urils (CB[n]s), and pillar[n]arenes (P[n]As) are the most common and deep-researched examples。They all have well-established and hydrophobic cavities which can encapsulate hydrophobic guests and provide ideal platforms for the fabrication of functional supramolecular materials
全文链接:
https://doi.org/10.1007/978-981-13-1744-6_65-1