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the efect of reaction temperature on the micro-nano structure and the capacitance properties of cryptomelane-type manganese oxide
writer:Fen Ran, Ying Liu
keywords:supercapacitor
source:期刊
Issue time:2015年

In this article,the uniform cryptomelane-type manganese oxide with an octahedral molecular sieves

structure was prepared under mild hydrothermal condition;the efects of hydrothermal temperature on the mi- cro-nanostructure and supercapacitance properties of manganese dioxide were studied in detail.The structures were characterized by SEM,XRD and TEM;and the supercapacitive behaviors were investigated with cyclic voltammetry,galvanostatic charge and discharge tests.The experiment results suggested that:the prepared nanoparticles can be self-organized into dendritic nanostructures,and the nanocluster arays are composed of nanonedles or tetragonal prism nanorods;with the increase of reaction temprature,the crystal morphology of

manganese oxide was gradualy improving,and was trasformed from nanonedles to tetragonal prism nanorods; the capacitance of MnO2 electrode was a combined contribution of electrical double-layer capacitance and pseud- ocapacitance,and the best specific capacitance value of MnO2 electrode was 603F/g coresponding to the charge/discharge cur rent density of 5 mA/cm2 ;with the increase of reaction temperature ranging from 100-180

°C ,the specific capacitance of manganese oxide gradualy decline.