writer：L. Xiao, L. Xu, Y. Yang, S. Zhang, Y. Huang, C. W. Bielawski, J. Geng,*
keywords：Fire-retardant, Carbon nanotubes, Polymer, Nanocomposites, Composite, Layer
source：期刊
specific source：ACS Omega 2017, 2, 2665–2671
Issue time：2017年

We report the preparation of polymer nanofibers with enhanced flame retardancy by coaxial electrospinning polyamide 66 (PA 66) and nanoscale graphene hybridized with red phosphorus (NG-RP). Transmission electron microscopy and energy-dispersive X-ray spectroscopy revealed that the nanofibers contained a NG-RP-based core surrounded by a PA 66 shell. The flame-retardant characteristics of the nanofibers were investigated by thermal gravimetric analysis, micro combustion calorimetry, and a series of vertical flame tests. The encapsulation of the NG-RP not only enhanced the flame-retardant characteristics of the nanofibers, but also improved their mechanical properties while maintaining the color and luster of the polymer, making the resultant nanofibers appropriate for use in a wide range of applications.