Neutral lutetium complex/polyamine mediated immortal ring-opening polymerization of rac-lactide: facile synthesis of well-defined hydroxyl-end and amide-core stereoregular star polylactide
writer:Wei Zhao, Bo Liu, Xinli Liu, Xue Wang, Yang Wang, Changguang Yao, Chunji Wu and Dongmei Cui
keywords:hydroxyl-end; stereoregular; rac-lactide; ROP; chain transfer agent
source:期刊
specific source:http://pubs.rsc.org/en/content/articlepdf/2015/py/c5py01164g
Issue time:2015年
A
highly efficient strategy for synthesizing hydroxyl-end and amide-core, highly
stereoregular, star-shaped polylactide was established by employing a lutetium
complexvia immortal ROP of rac-lactide with a polyamine
as the chain transfer agent.