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Isoprene polymerization with aminopyridinato ligand supported rare-earth metal complexes. Switching of the regio- and stereoselectivity
writer:Yang, Y ; Lv, K ; Wang, LF ; Wang, Y ; Cui, DM
keywords:1,3-butadiene polymerization, catalysts
source:期刊
specific source:http://pubs.rsc.org/en/Content/ArticleLanding/2010/CC/c0cc00297f#!divAbstract
Issue time:2010年
The highly cis-1,4, trans-1,4 and 3,4-selective polymerizations of isoprene were successfully regulated by simply modifying the auxiliary ligands, metal centres and initiation groups of rare-earth metal complexes and cocatalysts.