相关链接
联系方式
  • 通信地址:浙江省台州市椒江区市府大道1139号生命科学大楼D楼环境工程技术研究所
  • 邮编:318000
  • 电话:0576
  • 传真:
  • Email:zhuhuayue@126.com
当前位置:> 首页 > 论文著作 > 正文
2024-06 Inorg Chem Front: Construction of S-scheme heterojunctions of a Ti-doped Ce-MOF and BiOCl for e?cient photocatalytic selective oxidation of amine
作者:Danxia Zhao, *a,b Pengyu Wu,c Huayue Zhu,a,b Ru Jiang,a,b Jingwei Chen,a Chuhan Qiu,a Shengtao Jiang
关键字:MOF
论文来源:期刊
具体来源:INORGANIC CHEMISTRY FRONTIERS
发表时间:2024年

The solar-driven selective oxidation of amines to imines has attracted widespread attention due to its green and non-polluting nature, as well as its high selectivity. In this study, a unique S-scheme BiOCl/UiO-66(Ce/Ti) heterojunction was ?rst constructed as an organic aerobic photocatalyst. Under visible light irradiation with water as the sole solvent, the yield of the imine reached 98%. The S-scheme charge transfer mechanism was veri?ed through in situ X-ray photoelectron spectroscopy and electron paramagnetic resonance measurements, revealing the source of excellent photocatalytic activity. Additionally, the synergistic e?ect of the interface microenvironment generated by the interaction between OVs and Ce–Ti was found to play a signi?cant role in the photocatalytic oxidation process. This work emphasizes the importance of designing a heterojunction interface microenvironment (IME) for achieving e?cient photocatalytic selective oxidation of amines.