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2022Oxidative evolution of Z/E-diaminotetraphenylethylene
作者:Xin Lia, Yongbing Zhuang, Qichao Ran and Xiangyang Liu
关键字:Oxidative evolution, diaminotetraphenylethylene
论文来源:期刊
具体来源:Phys. Chem. Chem. Phys, 2022, DOI: 10.1039/d1cp05303e
发表时间:2022年

We report that Z/E-diaminotetraphenylethylene (Z/E-2NH2-TPE) molecules suffer primarily from oxidative evolution rather than recognized isomerization. The oxide is separated and its structure is deciphered by single crystal X-ray diffraction. The oxidative evolution

accompanying the rearrangement is explained through quantum theoretical calculation.