165. The synthesis of bottlebrush cellulose-graft diblock copolymer elastomers via atom transfer radical polymerization utilizing a halide exchange technique
writer:Juan Zhang, Zhongkai Wang, Xuehui Wang* and Zhigang Wang *
keywords:Bottlebrush, cellulose, PBA-b-PMMA
source:期刊
specific source:Chem. Commun., 2019, 55, 13904.
Issue time:2019年
A novel kind of bottlebrush cellulose-graft-diblock copolymer thermoplastic elastomer (Cell-g-PBA-b-PMMA) was synthesized by grafting from cellulose backbones via surface-initiated atom transfer radical polymerization (ATRP). The mechanical properties of the bottlebrush copolymer elastomers can be adjusted by controlling the block lengths and composition of the side chains.