High H2 Adsorption by Coordination-Framework Materials
作者:Xiang Lin, Junhua Jia, Xuebo Zhao, K. M. Thomas, A. J. Blake, G. S. Walker, N. R. Champness, P. Hubb
关键字:H2 Adsorption
论文来源:期刊
具体来源:Angew. Chem. Int. Edit., 2006, 45, 7358-7364.
发表时间:2006年
A series of coordination frameworks with different pore sizes (see structure of one; Cu blue, C gray, H white, O red) are prepared from CuII ions and carboxylate ligands of various lengths. Comparison of their sorption properties reveals that smaller pores allow higher densities of adsorbed H2, whereas larger pores allow higher maximum H2 storage capacities.