High CO2/N2 and CO2/CH4 Selectivity in A Flexible Chiral Metal Organic Framework Assembled from Difunctional Tridentate Ligand
writer:Xiaoxia Lv, Liangjun Li, Sifu Tang, Jinjun Cai, Chao Wang, Min Jiang, Xuebo Zhao,*,
keywords:CO2/N2 and CO2/CH4 Selectivity
source:期刊
specific source:Chem. Commun., 2014, Volume: 50, Issue: 52, Pages: 6886-6889
Issue time:2014年
A metal-organic framework with chiral pores and decorated imidazole and methyl groups was constructed. Upon activation, this MOF undergoes a pore contraction and shows very high selectivity for CO2/N2 and CO2/CH4, indicating a synergistic effect of dynamic pores and functional groups.