High gas storage capacities and stepwise adsorption in a UiO type metal-organic framework incorporating Lewis basic bipyridyl sites
writer：Liangjun Li, Sifu Tang, Chao Wang, Xiaoxia Lv, Min Jiang, Huaizhi Wu, Xuebo Zhao
keywords：UiO type metal-organic framework
source：期刊
specific source：ChemComm，2014，50, 2304-2307
Issue time：2014年
A UiO type MOF with Lewis basic bipyridyl sites was synthesized and structurally characterized. After being activated by Soxhlet-extraction, this MOF exhibits high storage capacities for H2, CH4and CO2, and shows unusual stepwise adsorption for liquid CO2 and solvents, indicating a sequential filling mechanism on different adsorption sites.