writer：Liangjun Li, Ying Wang, Xin Gu, Qipeng Yang,and Xuebo Zhao*
keywords：MOF,adsorption, selectivity
source：期刊
specific source：Chemistry – An Asian Journal,2016,11（13）
Issue time：2016年
The development of functional porous carbon with high CO2/N2 selectivity is of great importance for CO2 capture. In this paper, a type of porous carbon with doped pyridinic sites (termed MOFC) was prepared from the carbonization of a pyridyl-ligand based MOF. Four MOFCs derived from different carbonizing temperatures were prepared. Structural studies revealed high contents of pyridinic-N groups and nearly the same pore-size distributions for these MOFCs. Gas-sorption studies revealed outstanding CO2 uptake at low pressures and room temperature. Owing to the high content of pyridinic-N groups, the CO2/N2 selectivity on these MOFCs exhibits values of about 40–50, which are among the top values in carbon materials. Further correlation studies demonstrated that the CO2/N2 selectivities show a positive linear relationship with the surface density of pyridinic-N groups, thus validating the synergistic effect of the doped pyridinic-N groups on CO2 adsorption selectivity.