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【RSC Advances】Cobalt sulfide supported on nitrogen and sulfur dual-doped reduced graphene oxide for highly active oxygen reduction reaction
writer:Ying Zhang, Pingwei Li, Xuying Yin, Ya Yan, Ke Zhan, Junhe Yang and Bin Zhao
keywords:Cobalt sulfide, rGO
source:期刊
specific source:RSC Advances, 2017, 7: 50246-50253.
Issue time:2017年
Cobalt sulfide nanoparticles grown on nitrogen and sulfur dual-doped reduced graphene oxide sheets (Co–S/NS-rGO) were synthesized as an efficient electrocatalyst for the oxygen reduction reaction (ORR) by a facile one-step annealing process at 400–600 °C. The catalyst synthesized at 500 °C (Co–S/NS-rGO-500) exhibits the best ORR catalytic activity compared to the other samples, together with high four-electron selectivity and excellent stability in alkaline medium. Moreover, the Co–S/NS-rGO-500 composite also manifests good ORR activity and selectivity in acid solution. The facile synthesis approach and superior ORR performance in both alkaline and acid electrolytes make the Co–S/NS-rGO catalysts promising as an alternative to commercial Pt/C catalyst for fuel cells.