作者：Yan, Rui; Zhang, Yaoyao; Wang, Xiaohui; 等
关键字：emulsion polymerization
论文来源：期刊
具体来源：JOURNAL OF COLLOID AND INTERFACE SCIENCE
发表时间：2012年

www.sciencedirect.com/science/article/pii/S0021979711013920

Synthesis of porous poly(styrene-co-acrylic acid) (PS-co-PAA) microspheres through one-step soap-free emulsion polymerization is reported. Various porous PS-co-PAA microspheres with the particle size ranging from 150 to 240 nm and with the pore size ranging from 4 to 25 nm are fabricated. The porous structure of the microspheres is confirmed by the transmission electron microscopy measurement and Brunauer-Emmett-Teller (BET) analysis. The reason for synthesis of the porous PS-co-PAA microspheres is discussed, and the phase separation between the encapsulated hydrophilic poly(acrylic acid) segment and the hydrophobic polystyrene domain within the PS-co-PAA microspheres is ascribed to the pore formation. The present synthesis of the porous PS-co-PAA microspheres is anticipated to be a new and convenient way to fabricate porous polymeric particles. (C) 2011 Elsevier Inc. All rights reserved.