Hollow microspheres with covalent-bonded colloidal and polymeric shell by Pickering emulsion polymerization
作者：Dezhong Yin, Qiuyu Zhang*, Changjie Yin, Xingbo Zhao and Hepeng Zhang
关键字：hollow microspheres;Pickering emulsion polymerization;phase separation
论文来源：期刊
具体来源：Polymers for Advanced Technologies
发表时间：2011年
Hollow microspheres with SiO2/polymer binary shell were fabricated from Pickering emulsion stabilized solely by methacryloxypropyltrimethoxysilane-modified SiO2 particles, and were characterized by optical microscopy, scanning electron microscopy, Fourier transformation infrared spectrum, thermogravimetric analysis (TGA), and energy dispersive X-ray spectroscopy. The microspheres were templated by the Pickering droplets and the inner structure was affect by the proportion of crosslinking reagent. TGA result indicated that 60.3% of polymer in the shell was connected with SiO2 by covalent bond which was formed by copolymerization of styrene and the reactive C![[DOUBLE BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8fe.gif)
C group on SiO2 stabilizer.
http://onlinelibrary.wiley.com/doi/10.1002/pat.1865/full