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个人简介

张秋禹,“长江学者”特聘教授,博士生导师,西北工业大学应用化学研究所所长,中国化学会会员,陕西省化学会理事,中国材料研究学会高分子材料与工程分会委员,陕西省环境学会理事,中国颗粒学会理事等。《高分子材料》、《化学工程》、《粘接》等期刊编委。张秋禹教授曾获全国巾帼建功标兵、教育部新世纪优秀人才奖励计划、陕西省科技奖一等奖、二等奖三项、陕西省青年科技奖、教育部霍英东青年教授教学奖等奖励。主要研究方向为多孔聚合物材料、微纳米有机/无机材料杂化材料,仿生智能与功能性高分子材料等。研制了多种高效分离的多孔有机材料、具有电磁响应性的微纳米高分子杂化材料、自修复高分子复合材料。课题组迄今已在J.Mater.Chem. A, Appl. Catal. B, ACS AMI, Macromolecules等国际知名期刊发表论文200余篇。



研究方向

1.多孔聚合物、有机/无机杂化材料

2.微纳米有机/无机材料杂化机理

3.高性能聚合物复合材料及自修复性能

4.利用控制聚合和点击聚合实现分子结构设计

5.设计、合成具有电磁性能和外磁场响应的功能型高分子复合材料

个人经历

2009年至今

西北工业大学理学院教授,长江学者特聘教授

2004年至今

西北工业大学理学院副院长

2002-2004

英国Loughborough大学访问研究

2002-2003

西北工业大学化工系教授

1995-1999

西北工业大学材料学院攻读博士学位,材料学

1987-1990

科学院北京化学所攻读硕士学位,结构化学

1983-1987

北京化工学院攻读学士学位,分析化学

荣誉奖励

2008

长江学者特聘教授

2008

陕西省科技进步二等奖

2007

陕西省科技进步一等奖

2006

教育部新世纪优秀人才奖励计划

2003

陕西省青年科技奖

2002

教育部霍英东青年教师教学奖

3年主持的主要科研项目

1

国家自然科学基金

51173146

新型磁性多层次组装单元构建及磁场下组装响应机制研究

2

国家863项目

2012AA02A404

腮腺炎减毒活疫苗等病毒性疫苗关键技术及产品研发

3

国家重点基础研究
发展计划(973)

2010CB635111

微纳米高分子复合颗粒材料合成与应用基础研究

4

国家自然科学基金
重点项目

51433008

蛋白印迹响应性高分子磁性复合微球多层次结构调控与性能

5

基础科研项目

高分子复合材料自修复

6

西安市成果转化项目

新型高效聚合物固定化酶载体规模化制备和应用关键技术

部分最近论文(完整文章列表请通过二维码浏览张老师谷歌学术档案)


  1. 1. A series of nanoparticles with phase-separated structures by 1,1-diphenylethene controlled one-step soap-free emulsion copolymerization and their application in drug release[J]. Nano Research, 2017, 10(9):2905-2922.

    2. Morphology-dependent electrochemical supercapacitors in multi-dimensional polyaniline nanostructures[J]. Journal of Materials Chemistry A, 2017, 5.

    3. Fabrication of hollow mesoporous SiO 2-BiOCl@ PANI@ Pd photocatalysts to improve the photocatalytic performance under visible light, Applied Catalysis B: Environmental, 2017.

    4. Large-scale fabrication of polymer ellipsoids with controllable patches via the viscosity-induced deformation of spherical particles[J]. Polymer Chemistry, 2017, 8(25). 

    5. Preparation of Mechanoresponsive Hairy Particles Using Polymeric Surfactants in Emulsion Polymerization, Polymer Chemistry, 2017.

    6. Microencapsulation through thermally sintering Pickering emulsion-based colloidosomes, Soft Matter, 2017.

    7. Cetyl trimethyl ammonium bromide (CTAB) micellar templates directed synthesis of water-dispersible polyaniline rhombic plates with excellent processability and flow-induced color variation, Polymer, 2017(117) 30-36.

    8. Synergistic improvement of thermal conductivities of polyphenylene sulfide composites filled with boron nitride hybrid fillers, Composites Part A: Applied Science and Manufacturing, 2017(95) 267-273.

    9. Facile synthesis of imidazole microcapsules via thiol-click chemistry and their application as thermally latent curing agent for epoxy resins, Composites Science and Technology, 2017(142) 198-206.

    10.Preparation of lipase/Zn3(PO4)2, hybrid nanoflower and its catalytic performance as an immobilized enzyme[J]. Chemical Engineering Journal, 2016, 291:287-297. (IF:5.310)

    11. Synthesis of BiOBr/carbon quantum dots microspheres with enhanced photoactivity and photostability under visible light irradiation[J]. Applied Catalysis A General, 2016, 527:127-136.(IF:4.012)

    12. Highly thermally conductive flame-retardant epoxy nanocomposites with reduced ignitability and excellent electrical conductivities[J]. Composites Science and Technology, 2017, 139: 83-89.(IF=3.897)

    13. Dielectric thermally conductive boron nitride/polyimide composites with outstanding thermal stabilities via in-situ polymerization-electrospinning-hot press method. Composites Part A: Applied Science and Manufacturing, 2017, 94: 209-216.(IF=3.791)

    14. Preparation of lipase/Zn3(PO4)2, hybrid nanoflower and its catalytic performance as an immobilized enzyme[J]. Chemical Engineering Journal, 2016, 291:287-297.(IF:5.310)

    15. Synthesis of BiOBr/carbon quantum dots microspheres with enhanced photoactivity and photostability under visible light irradiation[J]. Applied Catalysis A General, 2016, 527:127-136.(IF:4.012) 

    16. Metallocenium Chemistry and Its Emerging Impact on Synthetic Macromolecular Chemistry[J]. ChemInform, 2016, 47(25):no-no.(IF:3.949)

    17. Highly thermally conductive flame-retardant epoxy nanocomposites with reduced ignitability and excellent electrical conductivities[J]. Composites Science and Technology, 2017, 139: 83-89.(IF=3.897)

    18. Dielectric thermally conductive boron nitride/polyimide composites with outstanding thermal stabilities via in-situ polymerization-electrospinning-hot press method. Composites Part A: Applied Science and Manufacturing, 2017, 94: 209-216.(IF=3.791)

    19. Deformation behavior of oriented β-crystals in injection-molded isotactic polypropylene by in situ X-ray scattering[J]. Polymer, 2016, 84: 254-266.(IF:3.586)

    20. Fabrication of modified bismaleimide resins by hyperbrnched phenyl polysiloxane and their improvement of thermal conductivities[J]. Rsc Advances, 2016, 6(62). (IF:3.289)

    21. Red-blood-cell-like BSA/Zn3(PO4)2, hybrid particles: Preparation and application to adsorption of heavy metal ions[J]. Applied Surface Science, 2016, 366(3):328-338.(IF:3.150)

    22. Functionalized graphite nanoplatelets/epoxy resin nanocomposites with high thermal conductivity[J]. International Journal of Heat & Mass Transfer, 2016, 92:15-22. (IF=2.857)

    23. Antagonistic effect of particles and surfactant on pore structure of macroporous materials based on high internal phase emulsion[J]. Colloids & Surfaces A Physicochemical & Engineering Aspects, 2016, 506:550-556.(IF:2.760)

    24. Fabrication and Properties of Thermally Conductive Epoxy Resin Nanocomposites Filled with fGNPs/PNBRs Hybrid Fillers[J]. Science of Advanced Materials, 2016, 8(5):972-979.(IF=1.8)

    25. Toughness Reinforcement in Carbon Nanotube-Filled High Impact Polypropylene Copolymer with β-Nucleating Agent[J]. Industrial & Engineering Chemistry Research, 2016, 55(32):8733-8742.(IF:2.567)

    26. Promoting Mechanochemistry of Covalent Bonds by Noncovalent Micellar Aggregation[J]. ACS Macro Letters, 2016, 5(9): 995-998.(IF:5.766)

    27. Impressed Pressure-Facilitated Seeded Emulsion Polymerization: Design the Fast Swelling Strategies for Massive Fabrication of Patchy Microparticles[J]. Polymer Chemistry, 2016. (IF:5.687)

    28. Fabrication of Liquid Protrusions on Non-Cross-Linked Colloidal Particles for Shape-Controlled Patchy Microparticles[J]. Macromolecules, 2016.(IF:5.554)

    29. One-step thiol-isocyanate dispersion polymerization: preparation of uniform, cross-linked and functional particles[J]. Chemical Engineering Journal, 2016, 304:461-468. (IF:5.310)

    30. Dependency of tunable microwave absorption performance on morphology-controlled hierarchical shells for core-shell Fe3O4@MnO2, composite microspheres[J]. Chemical Engineering Journal, 2016, 304:552-562. (IF:5.310)

    31. Synthesis of magnetically separable Fe 3 O 4 @PANI/TiO 2, photocatalyst with fast charge migration for photodegradation of EDTA under visible-light irradiation[J]. Chemical Engineering Journal, 2016, 303:282-291. (IF:5.310)

    32.  Effect of the Structure and Length of Flexible Chains on Dendrimers Grafted Fe3O4@SiO2/PAMAM Magnetic Nanocarriers for Lipase Immobilization [J].ACS Sustainable Chemistry & Engineering. 2016.(IF:5.267)

    33. Amino-Fe3O4 Microspheres Directed Synthesis of a Series of Polyaniline Hierarchical Nanostructures with Different Wettability[J]. Scientific Reports, 2016, 6.(IF:5.228)

    34. Hyperbranched polysiloxane (HBPSi)-based polyimide films with ultralow dielectric permittivity, desirable mechanical and thermal properties[J]. Journal of Materials Chemistry C, 2016, 4(11):2134-2146. (IF:5.066)

    35. Preparation of anti-nonspecific adsorption polydopamine-based surface protein-imprinted magnetic microspheres with the assistance of 2-methacryloyloxyethyl phosphorylcholine and its application for protein recognition[J]. Sensors & Actuators B Chemical, 2017, 241:413-421.(IF:4.758)

    36. Design of Raspberry‐Shaped Microcarriers with Adjustable Protrusions and Functional Groups for the Improvement of Lipase Immobilization and Biocatalysis: Environmentally Friendly Esterification of Oleic Acid for Biodiesel ,ChemCatChem, 2016, 8(16):2574-2574.(IF:4.724)

    37.Tunable Permittivity in High–Performance Hyperbranched Polyimide Films by Adjusting Backbone Rigidity[J]. Journal of Physical Chemistry C, 2016, 120(5).(IF:4.509)

    38. Novel BiOCl/TiO 2, hierarchical composites: Synthesis, characterization and application on photocatalysis[J]. Applied Catalysis A General, 2016, 516:81-89. (IF:4.012)

    39. Rapid and efficient synthesis of isocyanate microcapsules via thiol-ene photopolymerization in Pickering emulsion and its application in self-healing coating[J]. Composites Science & Technology, 2016, 123(4):250-258.(IF:3.897) 

    40. Robust, self-healing, superhydrophobic coatings highlighted by a novel branched thiol-ene fluorinated siloxane nanocomposites[J]. Composites Science & Technology, 2016, 137:78-86. (IF:3.897)

    41. Preparation of Light Core/Shell Magnetic Composite Microspheres and Its Application to Lipase Immobilization[J]. Rsc Advances, 2016, 6(70). (IF:3.289) 

    42. “Ultrahigh humidity sensitivity of NaCl-added 3D mesoporous silica KIT-6 and its sensing mechanism” RSC Advances, 2016, 6, 38391 – 38398. (IF:3.289)

    43. Preparation of One-dimensional Fe3O4@P(MAA-DVB)-Pd(0) Magnetic Nanochains and Its application for rapid degradation of Organic Dyes[J]. Rsc Advances, 2016. (IF:3.289)

    44. Facile synthesis of LiCo1/3Ni1/3Mn1/3O2/Al(OH)3 composite as a high-performance cathode material for lithium ion cells[J]. Journal of Alloys & Compounds, 2016, 656:849-853.(IF:3.014)

    45. Facile synthesis and enhanced electromagnetic microwave absorption performance for porous core-shell Fe3O4@MnO2, composite microspheres with lightweight feature[J]. Journal of Alloys & Compounds, 2016, 693:432-439. (IF:3.014) 

    46. Fabrication and Characterization of Electrospun Dopants/PS Composite Fibers with Porous and Hollow‐Porous Structures[J]. Macromolecular Materials & Engineering, 2016, 301(5):625-635. (IF:2.834)

    47. Preparation of quaternary amine monolithic column for strong anion-exchange chromatography and its application to the separation of Enterovirus 71.[J]. Journal of Chromatography B, 2016, 1033-1034:399-405.(IF:2.687)

    48. Well-Defined Core-Shell Fe3O4@Polypyrrole Composite Microspheres with Tunable Shell Thickness: Synthesis and Their Superior Microwave Absorption Performance in the Ku Band[J]. Industrial & Engineering Chemistry Research, 2016, 55(22).(IF:2.567) 

    49. Multidimensional polyaniline structures from micellar templates[J]. Journal of Materials Science,1-8.(IF:2.302)

    50. Hypercrosslinked polymers: controlled preparation and effective adsorption of aniline[J]. Journal of Materials Science, 2016, 51(18):8579-8592. (IF:2.302)

    51. Immobilization of lipase on mesoporous silica nanoparticles with hierarchical fibrous pore[J]. Journal of Molecular Catalysis B: Enzymatic, 2016, 134: 129-135.(IF:2.189)

    52. Synthesis of magnetically separable core–shell structured NixFe1?x Fe2O4@TiO2, nanoparticles photocatalysts for the degradation of organic dyes[J]. Journal of Porous Materials, 2016:1-8.(IF:1.385) 

    53. Grafting–through Strategy in Emulsion: An Eco–friendly and Effective Route for the Synthesis of Graft Copolymers[J]. ChemistrySelect,2016, 1(9):1870-1878.

    54. Effect of carboxyl density at the core–shell interface of surface-imprinted magnetic trilayer microspheres on recognition properties of proteins[J]. Sensors and Actuators B: Chemical, 2014, 196:265-271.

    55. Preparation and characterization of bovine serum albumin surface-imprinted thermosensitive magnetic polymer microsphere and its application for protein recognition[J]. Biosensors and Bioelectronics, 2014, 51:261-267.

    56. One-pot hydrothermal synthesis of highly monodisperse water-dispersible hollow magnetic microspheres and construction of photonic crystals[J]. Chemical Engineering Journal, 2015, 259:779-786.

    57. Fast and facile fabrication of porous polymer particles via thiol–ene suspension photopolymerization[J]. Rsc Advances, 2014, 4:13334-13339.

    58. Facile fabrication of Fe3O4@PS/PGMA magnetic Janus particles via organic-inorganic dual phase separation[J]. Rsc Advances, 2014, 4, 27152-27158.

    59. Synthesis and Characterization of Comb and Centipede Multigraft Copolymers P n BA-g-PS with High Molecular Weight Using Miniemulsion Polymerization[J]. Macromolecules, 2014, 47,7284-7295.

    60. Fabrication of highly dispersed ZnO nanoparticles embedded in graphene nanosheets for high performance supercapacitors[J]. Electrochimica Acta, 2014, 148:164-169.

    61. Time-dependent control of phase and morphology transformation of porous ZnO hollow microspheres by a facile one-step solution route[J]. Rsc Advances, 2014, 4:7167-7173.

    62. Nanosheet-based 3D hierarchical ZnO structure decorated with Au nanoparticles for enhanced electrochemical detection of dopamine[J]. Rsc Advances, 2014, 4:48986-48993.

    63. Novel Janus magnetic micro particle synthesis and its applications as a demulsifier for breaking heavy crude oil and water emulsion[J]. Fuel, 2015, 141: 258–267.

    64. Colloidal particles with various glass transition temperatures: preparation, assembly, and the properties of stop bands under heat treatment[J]. Journal of Materials Science, 2014, 49:2653-2661

    65. Thermal conductivities,mechanical and thermal properties of graphite nanoplatelets/polyphenylene sulfide composites[J]. Rsc Advances, 2014, 4:22101-22105.

    66. Pickering emulsion: A novel template for microencapsulated phase change materials with polymer–silica hybrid shell[J]. Energy, 2014, 64:575-581.

    67. Improved space survivability of polyhedral oligomeric silsesquioxane (POSS) polyimides fabricated via novel POSS–diamine[J]. Corrosion Science, 2014, doi:10.1016/j.corsci.2014.10.013.

    68. Synthesis and gas permeation properties of hyperbranched polyimides membranes from novel(A2+ B2B′+B2)-type method. Journal of Membrane Science,2014,450: 138-146.

    69. Space Survivable Polyimides with Excellent Optical Transparency and Self-Healing Properties Derived from Hyperbranched Polysiloxane, ACS Appl. Mater. Interfaces, 2013,5:10207–10220

    70. Synthesis of Raspberry-Like Poly(styrene–glycidyl methacrylate) Particles via a One-Step Soap-Free Emulsion Polymerization Process Accompanied by Phase Separation. Langmuir. 2013,29: 11730-11741.

    71. Preparation and characterization of novel immobilized Fe3O4@SiO2@mSiO2–Pd(0) catalyst with large pore-size mesoporous for Suzuki coupling reaction. Applied Catalysis A: General.2013,459: 65-72.

    72. Synthesis of poly (methyl methacrylate)-b-polystyrene with high molecular weight by DPE seeded emulsion polymerization and its application in proton exchange membrane. Journal of Colloid and Interface Science. 2013,406: 154-164.

    73. Preparation of thermoresponsive Fe3O4/P(acrylic acid–methyl methacrylate–N-isopropylacrylamide) magnetic composite microspheres with controlled shell thickness and its releasing property for phenolphthalein. Journal of Colloid and Interface Science. 2013,398: 51-58.

    74. One-Pot Synthesis of Highly Magnetically Sensitive Nanochains Coated with a Fluorescent Shell by Magnetic-Field-Induced Precipitation Polymerization. Science of Advanced Materials. 2013,5: 623-629.

    75. Synthesis of BSA/Fe3O4magnetic composite microspheres for adsorption of antibiotics. Materials Science and Engineering: C.2013,33: 4401-4408.

    76. Preparation and characterization of structure-tailored magnetic fluorescent Fe3O4/P(GMA–EGDMA–NVCz) core–shell microspheres. Journal of Materials Science.2013,48: 5302-5308.

    77. Encapsulation and dispersion of carbon black by an in situ controlling radical polymerization of AA/BA/St with DPE as a control agent, Colloid and Polymer Science, 2013,291: 2399-2408.

    78. Three new conjugated polymers based on benzo[2,1-b:3,4-b '']dithiophene: synthesis, characterization, photoinduced charge transfer and theoretical calculation studies, Polymer Chemistry .2012,3: 2244-2253.

    79. Fabrication of one-dimensional Fe3O4/P(GMA-DVB) nanochains by magnetic-field-induced precipitation polymerization. Journal of Colloid and Interface Science.2012,374: 339-344.

    80. Synthesis of block copolymer poly (n-butyl acrylate)-b-polystyrene by dpe seeded emulsion polymerization with monodisperse latex particles and morphology of self-assEMBLY film surface.Journal of Colloid and Interface Science.2012,374: 54-60.

    81. Humidity sensing mechanism of mesoporous MgO/KCl–SiO2 composites analyzed by complex impedance spectra and bode diagrams”. Sensors and Actuators B 174 (2012) 513– 520

    82. Fabrication of 1D Fe3O4/P(NIPAM-MBA) thermosensitive nanochains by magnetic-field-induced precipitation polymerization. Colloid and Polymer Science.2012,290: 1207-1213.

    83. Synthesis of block copolymer poly (n-butyl acrylate)-b-polystyrene by DPE seeded emulsion polymerization with monodisperse latex particles and morphology of self-assembly film surface, Journal of colloid and interface science, 2012, 374: 54-60

    84. Synthesis of two conjugated polymers as TNT chemosensor materials. Sensors and actuators B: chemical, 2010, 149: 155-160

    85. Preparation and characterization of magnetic composite microspheres using a free radical polymerization system consisting of DPE, Polymer, 2009, 50:1887-1894

    86. Calculation of band gap in long alkyl-substituted heterocyclicthiophene-conjugated polymers with electron donor–acceptor fragment, Solar energy materials and solar cells, 2008, 92:581-587

    87. A molecular simulation study of a series of cyclohexanone formaldehyde resins: Properties and applications in plastic printing. Polymer, 2007, 48: 887-893

    88. Preparation of high-magnetization Fe3O4–NH2–Pd (0) catalyst for Heck reaction. Catalysis communications, 2012, 17: 168-172

    89. Supported nanosized palladium on superparamagnetic composite microspheres as an efficient catalyst for Heck reaction. Catalysis communications, 2010,11:606-610

    90. Fabrication of 1D Fe3O4/P(NIPAM-MBA) thermosensitive nanochains by magnetic-field-inducedprecipit ation polymerization. Colloid and polymer science, 2012, 290:1207-1213