作者：Zhang, Liu Xing，Zhang, Yong Cai，Zhang, Ming
关键字：Nanostructures; Semiconductors, Chemical synthesis, Electron microscopy
论文来源：期刊
具体来源：Materials Chemistry and Physics
发表时间：2009年
Without the assistance of any template and surfactant, In₂S₃ microspheres constructed with nanoflakes or nanoparticles were controllably synthesized via the hydrothermal reaction of InCl₃·4H₂O and Na₂S₂O₃·5H₂O in 6.25 vol.% acetic acid aqueous solution (pH = 3) at 150–180 °C for 6–24 h. The nanostructured In₂S₃ can be completely transformed into In₂O₃ when subjected to calcination in air at 600–700 °C for 5 h. The In₂O₃ produced at 600 °C consisted of microspheres built up with the nanoparticles of 20–30 nm in diameter. X-ray diffraction, X-ray photoelectron spectroscopy, energy dispersive X-ray spectroscopy, field emission scanning electronic microscope, Raman and photoluminescence spectra have been used to characterize the structures, compositions and optical properties of the obtained products.