作者：Qitao Zhang，Bin Xu，Saisai Yuan，Ming Zhang，Teruhisa Ohno
关键字：CeO2 nanoparticle, Polystyrene microsphere, Surface modification, Composite materials, Electrostatic interaction
论文来源：期刊
具体来源：Materials Letters
发表时间：2014年
CeO₂-based hybrid materials represent a unique class of functional composites with various applications in catalysis, sensors, solid oxide fuel cells, solar cells, and mechanical polishing. In this work, based on electrostatic interaction between carboxylic groups and rare earth cations, a facile and feasible approach to fabricate sesame ball-like CeO₂:Y³⁺/P(St–AA) composite microspheres with excellent stability was established. Carboxylic functionalized mondisperse P(St–AA) microspheres were prepared by soap-free emulsion polymerization and then by composition with positively charged CeO₂:Y³⁺nanoparticles (NPs) at ambient temperature. The morphology of as-prepared samples was observed by SEM, TEM, and HAADF-STEM characterizations, and XRD, FT-IR, zeta-potential, EDS, DLS and conductometric titration were also used to investigate the structure and formation mechanism of the composite microspheres. With the advantages of tunable functional groups and loaded ions on the surface of P(St–AA) microspheres and CeO₂:Y³⁺NPs, respectively, this method could be further expanded for the preparation of various oxide/polymer hybrid composite microspheres.