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Application of a Parallel Synthetic Approach in Atom‐Transfer Radical Polymerization: Set‐Up and Feasibility Demonstration
作者:Huiqi Zhang, Martin W. M. Fijten, Richard Hoogenboom, Roy Reinierkens, Ulrich S. Schubert*
关键字:Parallel synthesis, atom transfer radical polymerization, set-up, feasibility demonstration
论文来源:期刊
具体来源:Macromolecular Rapid Communications
发表时间:2003年
A parallel synthetic approach toward homogeneous atom-transfer radical polymerization of methyl methacrylate has been successfully applied by utilizing an automated synthesizer. Experimental set-up, automated parallel synthesis and purification of the polymers via a solid-phase extraction set-up, as well as online and offline measurements of the molecular weights and monomer conversion are described in detail. In addition, a comparison with conventional experiments in the laboratory is provided.