[Polym. Int.] Polymer grafts on zirconia particles and their application as supports of hybrid catalyst
作者：Jiming Yang, Ning Zhang, Haolong Li, Bin Xu, Wenjing Tian and Dewen Dong
关键字：polymer grafts, zirconia particle, self-initiated photografting and photopolymerization
论文来源：期刊
发表时间：2015年
A facile and efficient strategy for the preparation of polymer grafts on zirconia particles is developed bymeans of self-initiated photografting and photopolymerization. The UV-induced grafting polymerization is applicable to a variety of polymerizable monomers, allowing the direct formation of homogeneous and stable polymer coatings on zirconia particles without any initiator immobilization. The as-prepared polymer grafts are proved to be efficient supports for polyoxometalates asH3PW12O40 can be uniformly and stably immobilized on a poly(4-vinylpyridine) layer through electrostatic interaction. The resulting hybrid catalyst system, associated with high catalytic activity for a series of oxidation reactions such as amines, alkenes, alcohols and sulfides, represents a novel and efficient system with a high catalyst loading capacity and stability upon reuse in further cycles.