祝贺侯丽曼的工作被ACS Macro Lett.接收!
We present the first example of surface-initiated
polymerization mediated by Lewis pairs for the synthesis of
polymer brushes on planar substrates. The method enables the
rapid grafting polymerization from self-assembled monolayer or surface-attached macroinitiators, furnishing linear polymer brushes and
bottle-brush brushes. Both homopolyester and block copolyester brushes can be
synthesized via this versatile approach. This work not only opens up
new opportunities for the application of Lewis pair-mediated polymerization,
but also enriches the surface-initiated polymerization on different surfaces.