writer：Ning Zhang, Stephan Salzinger, Frank Deubel, Rainer Jordan, and Bernhard Rieger
keywords：group transfer polymerization, rare earth metal, polymer brushes
source：期刊
specific source：JACS
Issue time：2012年

We present the first example of a surfaceinitiated group transfer polymerization (SI-GTP) mediated by rare earth metal catalysts for polymer brush synthesis. The experimentally facile method allows rapid grafting of polymer brushes with a thickness of >150 nm in <5 min at room temperature. We show the preparation of common
poly(methacrylate) brushes and demonstrate that SI-GTP is a versatile route for the preparation of novel polymer brushes. The method gives access to both thermoresponsive and proton-conducting brush layers.

http://pubs.acs.org/doi/abs/10.1021/ja3027423?mi=uvozc9&af=R&pageSize=20&searchText=peptide