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A 1,8-naphthyridine-based fluorescent chemodosimeter for the rapid detection of Zn2+ and Cu2+
writer:Yu, M. M.; Li, Z. X.; Wei, L. H.; Wei, D. H.; Tang, M. S.
keywords:fluorescent chemodosimeter
source:期刊
specific source:Org. Lett. 2008, 10, 5115–5118
Issue time:2008年

A novel fluorescent chemodosimeter based on 1,8-naphthyridine exhibits high selectivity to Zn2+ and Cu2+. When 1-(7-acetamino-1,8-naphthyridyl)-
2-(6-diacetaminopyridyl)ethene was mixed with CuCl2, hydrolysis of the acetamino group catalyzed by Cu2+ complex was first observed.
Resulting from coordination and hydrolysis catalyzed by the corresponding complex of Zn2+ or Cu2+, the highly effective fluorescent detection
of Zn2+ and Cu2+ is realized with Zn2+-selective dual-emission and Cu2+-selective ON-OFF behavior.