Green one-step synthesis of ZnO/cellulose nanocrystal hybrids with modulated morphologies and superfast absorption of cationic dyes
主要译著者:Ying Guana, Hou-Yong Yu, Somia Yassin Hussain Abdalkarim, Chuang Wanga, Feng Tang,&et.al
出版机构:International Journal of Biological Macromolecules
出版日期:2019-3-10
Zinc oxide/cellulose nanocrystal (ZnO/CNC) hybrids with modulated morphologies were prepared by using bamboo CNC as templates via green one-step technique. The effect of pH values on the morphology, microstructure, thermal stability, antibacterial efficiency and dye absorption kinetics of hybrids were investigated. A possible mechanism for various hybrid morphologies at different pH values was provided. All the samples exhibited high antibacterial ratios of 91.4%-99.8% against both Escherichia coli and Staphylococcus aureus. ZnO/CNC8.5gave quick removal efficiency with high dye removal ratios in methylene blue (MB, 93.55%) and malachite green (MG, 99.02%), especially more than 91.47% and 97.85% within 5 minutes. The absorption capacity could reach up to 46.77 mg/g for MB and 49.51 mg/g for MG. Besides, absorption kinetics showed that the absorption behavior followed the pseudo-second-order kinetic model (R2 >0.99996). Such ZnO/CNC hybrids show outstanding and low-cost adsorbent for efficient absorption of cationic dyes in wastewater treatment field.