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Copolymer logical switches adjusted through core-shell micelles: from temperature response to fluorescence response.
writer:Qiang Yan, Jinying Yuan*, Weizhong Yuan, Mi Zhou, Yingwu Yin and Caiyuan Pan*
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source:期刊
specific source:Chemical Communications,2008,46,6188-6190
Issue time:2008年

Aqueous solution of micelles prepared from novel PS-b-PNIPAM with fluorescent group CEA at the junction between two blocks displays logical responsive switches on temperature and fluorescence; at lower temperature, stretching of PNIPAM chains causes high mobility of CEA leading to formation of more excimer species; at higher temperature, shrinking of PNIPAM chains isolates the fluorescent groups between the core and shell, resulting in fewer excimer species.