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Smart Self-Assemblies Based on Surfactant-encapsulated Photoresponsive Polyoxometalate Complex
作者:Yi Yan, Huanbing Wang, Bao Li, Guangfeng Hou, Zhendong Yin, Lixin Wu,* and
关键字:isomerization,photochemistry,polyoxometalates,self-assembly,supramolecular chemistry
论文来源:期刊
具体来源:Angew. Chem. Int. Ed. 2010, 49, 9233-9236.
发表时间:2010年

Smart POMs: A surfactant-encapsulated organic-grafted polyoxometalate (POM) is synthesized by grafting a photoresponsive azobenzene group to an Anderson-type POM cluster. Self-assemblies of the hybrid complexes exhibit photocontrolled reversible aggregation and morphological change as a result of photoisomerization-induced structural alternation (see figure).