【Mol. Cryst. Liq. Cryst., 2008, 493, 65-70】Fluoro- and nitro-substitution effect of some chiral compounds
writer:Yongmin Guo, Lifeng Bi, Baozong Li, Yonggang Yang, and Jianxun Wen
keywords:chiral
source:期刊
specific source:Mol. Cryst. Liq. Cryst
Issue time:2008年
Yongmin Guo, Lifeng Bi, Baozong Li, Yonggang Yang, and Jianxun Wen
Mol. Cryst. Liq. Cryst., 2008, 493, 65-70.
Four chiral compounds have been synthesized. Their phase transition behavior was investigated by differential scanning calorimetry and polarized optical microscopy. Two of them show monotropic smectic C phases. Moreover, one of them shows an enantiotropic blue phase. The lateral fluoro-substitution strongly suppressed the formation of SmC phases and decreased clearing points. Although the introduction of nitro group in the core decreased the length-diameter ratio, the temperature range of monotropic SmC phase did not change much.