【Nanotechnology, 2008, 19, 355603.】Handedness inversion in preparing mesoporous silica nanoribbons
writer:Yuanli Chen, Yongmin Guo, Huanyu Zhao, Lifeng Bi, Xianfeng Pei, Baozong Li, and Yonggang Yang
keywords:nanoribbons
source:期刊
specific source:Nanotechnology
Issue time:2008年
Yuanli Chen, Yongmin Guo, Huanyu Zhao, Lifeng Bi, Xianfeng Pei, Baozong Li, and Yonggang Yang
Nanotechnology, 2008, 19, 355603.
Abstract:
A new chiral cationic amphiphile has been synthesized. Sol–gel transcriptions were carried out to control mesoporous silica nanostructures using the organic self-assemblies of this amphiphile as templates. Left-handed coiled mesoporous silica nanoribbons were obtained in the mixture of 1-propanol and 2.5 wt% NH3 aq. at the ratio of 2:8 and 0 。C. However, right-handed coiled mesoporous silica nanoribbons were prepared in 2.5 wt% NH3 aq. at 25 。C. The organization of the low-molecular-weight gelators plays an important role in this handedness inversion.