writer：Yu, Z.; Wang, L.; Liu, L.; Wang, M.; Yang, H.*
keywords：Polymer synthesis
source：期刊
specific source：Synlett, 2022, 33, 1607-1618.
Issue time：2022年

Olefin metathesis polymerization has commanded great attention

as a versatile method for preparing macromolecular materials

with advanced architectures and functions in academia and industry.

This Account summarizes our endeavors directed towards the preparation

of various functional polymers by using olefin metathesis polymerization

strategies in particular acyclic diene metathesis (ADMET) polymerization

and ring-opening metathesis polymerization (ROMP), during

the last ten years. In addition, the merits and limitations of ADMET polymerization

and ROMP techniques are also demonstrated and compared.

Notably, this Account highlights our recently developed sequence-

controlled ROMP strategy for production of precision polymers

in a regio-/stereoselective manner, the rollercoaster journey for the

evolution of a macrobicyclic olefin system containing a sacrificial silyloxide

bridge is described in detail.