writer:Facui Yang, Qingmin Yang, Mengmeng Chen, Chunyan Luo, Weixing Chen, Peng Yang
keywords:Protein, adsorption,heavy metal ions ,water treatment
source:期刊
Issue time:2021年
Biomass materials have gained considerable attention as sustainable and renewable resources for the production of adsorbents. However, there remain significant challenges to their application scale-up, such as complex production or processing methods, poor stability, high cost, and low adsorption capacity. Herein, we report an inexpensive environmentally friendly protein-polysaccharide complex that exhibits excellent removal efficiency of toxic metal ions. Through amyloid-like coacervation, a bovine serum albumin (BSA) and sodium carboxymethyl cellulose (CMC) complex, which is a potent toxic metal ion sequester, can be formed within 1 min. The adsorbent is effective for the simultaneous removal of multiple toxic metal ions species (Hg2+, Cr3+, Pb2+, Cd2+, As3+, Ni2+, and Co2+) and radioactive elements (uranium) from tap water (at <1 ppm) in 10 min, meeting World Health Organization limits. Moreover, the biomass adsorbent can efficiently capture uranium ions (188.2 mg/g) from simulated seawater, which is 4.5 times higher than that achievable with pristine activated carbon, at a 13–360-fold cost reduction. The biomass material offers noticeable scale-up advantages because of its low cost, easy regeneration, and good toxic metal ion removal efficiency from multi-element toxic metal aqueous solutions.