Synthesis of fully alternating polycarbonate with low Tg from carbon dioxide and bio-based fatty acid
作者：Ying-Ying Zhang, Xing-Hong Zhang,* Ren-Jian Wei, Bin-Yang Du, Zhi-Qiang Fan and Guo-Rong Qi
关键字：Carbon dioxide，Polycarbonate，Double metal cyanide complex, Fatty acid
论文来源：期刊
具体来源：RSC Adv., 2014, 4, 36183–36188
发表时间：2014年
The selective copolymerization of CO2 and an epoxide to form fully alternating polycarbonates is a great challenge via catalysis with the zinc–cobalt(III) double metal cyanide complex [Zn–Co(III) DMCC]. We describe the first perfectly alternating copolymerization of CO2 with a bio-based epoxide. The resultant polycarbonate had a low Tgs of 38 to 44 C and two end hydroxyl groups, which were then used to initiate ring-opening polymerization of L-lactide via metal-free catalysis, affording a biodegradable triblock copolymer. This study provides a new platform copolymer for making various advanced polymers with biodegradable properties.
