Kinetics and Mechanism of Bulk Polymerization of Styrene Catalyzed by Rare Earth Catalyst
writer:Wu Linbo, Li Bogeng*, Li Baofang, Cao Kun
keywords:styrene,polymerization,rare earth catalyst,kinetics,mechanism
source:期刊
specific source:Chinese Journal of Chemical Engineering, 9(4): 376-381, 2001.11
Issue time:2001年
The bulk polymerization of styrene catalyzed by Nd(P204)3/MgBu2. AlEt3/HMPA was carried out in capped glass tubes. The effects of reaction conditions on polymerization conversion and molecular weight in the range of high conversion were investigated . The molecular weight of the resultant polymers is dramatically high and its distribution is relatively narrow.