Journal of Polymer Science Part B: Polymer Physics, 2010, 48, 479-489.

ABSTRACT:

The biodegradable polylactide composites containing carbon nanotubes (CNTs) with high aspect ratio (HAR) and low aspect ratio (LAR) were prepared by melt mixing. The physical properties of those two systems were characterized in terms of rheology, conductivity and mechanical properties for establishing preliminary structure-property relations. Several viscoelastic models were then used to further describe the relations between aspect ratio and percolation network of CNTs. The results show that these two CNTs present different structural characteristics in the polylactide (PLA) matrix during melt mixing: the LAR CNTs are far stiffer than the HAR CNTs. At low loading levels, the former is dispersed as bent fibers or their small bundles; while the latter is dispersed as self-entangled flocs, presenting far larger hydrodynamic radius than the former. At high loading levels, both are dispersed as flocs due to strong tube-tube interactions. However, the two CNTs show approximate average floc size and mesh size because they present same rigid length and effective aspect ratio. At identical loadings, therefore, the HAR CNTs have more total number of flocs than that of the LAR CNTs, forming network with more compact structure and imparting higher contributions to properties of the composites as a result.

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http://www3.interscience.wiley.com/journal/123238579/abstract