作者：Jing Huang, Yaxin Qiu, Defeng Wu, Jun Wang
关键字：Thermoplastic polyester elastomer; Spodumene slag; Composites; Thermal stability; Mechanical properties.
论文来源：期刊
具体来源：Industrial & Engineering Chemistry Research
发表时间：2017年

Industrial & Engineering Chemistry Research, 2017, 56, 6239-6246 

ABSTRACT

A new approach to improve the thermal stability and mechanical strength of thermoplastic polyester elastomer (TPEE) using spodumene slag as the filler is reported here. The thermal decomposition temperature of TPEE increases from 277 ^oC to about 350 ^oC by about 26% in the presence of pristine spodumene slag. The surface graft reaction further improves its barrier effect. Besides, spodumene slag can be used as good reinforcement to TPEE, and also the surface treatment favors further improvement of its reinforcing effect. But the presence of spodumene slag reduces elastoplasticity and viscoplasticity of system, leading to decreased tensile cycles and elongation levels. The morphological and crystallographic methods were then employed to further reveal the alteration of phase separation structure of TPEE in the presence of spodumene slag, aiming at establishing structure-property relations of composites. This work can provide useful information on the preparation of new TPEE composites with tailorable properties.

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http://pubs.acs.org/doi/abs/10.1021/acs.iecr.7b00904