writer：Guorui Zhang, Defeng Wu,* Wenyuan Xie, Zhifeng Wang, Chunjiang Xu
keywords：starch nanocrystal (SNC); surface acetylation; poly(β-hydroxybutyrate) (PHB); nanocomposite; nucleation; spherulite.
source：期刊
specific source：Carbohydrate Polymers
Issue time：2018年

Carbohydrate Polymers, 2018, 195C, 79-88. 

ABSTRACT:

 

Starch nanocrystal (SNC) particles were used as the filler to prepare green composites with biodegradable poly(β-hydroxybutyrate) (PHB). An interesting way to tune the nucleation and banded morphology of composites by the surface acetylation of SNC was proposed. Pristine SNC acts as the nucleating agent, while acetylated SNC as the antinucleation one to PHB. This role switching is due to improved polymer-particle compatibility after surface acetylation of SNC particles. The banded structure of PHB spherulites degrades evidently in the presence of two kinds of SNC particles, showing decreased ring-band space, with deteriorated periodicity and increased flocculation of peak-to-valley height. But the two kinds of composites have different mechanisms on the degradation of their ring-bands because the two kinds of SNC particles, pristine SNC and acetylated one, have different influences on the PHB spherulite growth rates and system undercooling. This work also opens a new window for the applications of SNC particles. 

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https://www.sciencedirect.com/science/article/pii/S0144861718304739