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24. Lignin and Soy Oil-Derived Polymeric Biocomposites by “Grafting from” RAFT Polymerization
作者:Yuzhi Xu, Liang Yuan, Zhongkai Wang, Perry Wilbon, Chunpeng Wang, Fuxiang Chu and Chuanbing Tang
关键字:Lignin, plant oil, graft elastomer
论文来源:期刊
具体来源:Green Chemistry
发表时间:2016年

“Grafting from” RAFT polymerization was carried out on lignin using three soybean oil-derived methacrylate monomers toward sustainable biocomposites. These grafted biocomposites showed structure-dependent thermal and mechanical properties. The presence of hydrogen bonding between secondary amides resulted in grafted copolymers with much higher glass transition temperature and different tensile behaviors. Epoxy resins prepared from epoxide-containing grafted polymers exhibited much tougher mechanical properties compared with uncured biocomposites.