writer：Yan Chao Xu a , Zhen Xing Wang a , Xi Quan Cheng a , You Chang Xiao b , Lu Shao
keywords：Nanofiltration
source：期刊
Issue time：2016年

Herein, a novel positively charged nanofiltration (NF) membrane has been facilely fabricated via a highly

efficient one-step mussel-substance-simulated co-deposition of low-cost catechol and branched

polyetheylenimine (PEI) onto substrates. The co-deposition behaviour, physicochemical properties and

separation performances of resultant membranes can be readily tailored by varying PEI molecular weight.

In particular, the catechol/PEI600 co-deposited NF membrane shows good removals toward dyes, common

salts and heavy metal ions for textile wastewater treatment. Our membranes exhibit high removal efficiency toward cationic dye and metal ions due to the Donnon effect. In addition, EtOH activation process

can greatly enhance the membrane permeance with a factor of 1.8–2.4 without compromising rejection.

Especially, the novel membranes show stable long-term separation performance toward MgCl2removal,

and the dye-fouled co-deposited membranes can be facilely regenerated and reused with a simple static

immersion operation. The co-deposited membrane can perform well in alcohols solvents, indicating its

excellent performance for practically environmentally-friendly usages. The facile strategy disclosed in

our study can provide new opportunities to not only nanofiltration membrane modification but also the

surface engineering of vast kinds of materials towards energy and environmental applications