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Preparation and catalysis of NaY-encapsulated Mn(III) Schiff-base complex in presence of molecular oxygen
作者:Rong-Min Wang ,Hui-Xia Feng ,Yu-Feng He ,Chun-Gu Xia ,Ji-Shuan Suo ,Yun-Pu Wang
关键字:Epoxidation; Zeolite encapsulated catalyst; Mn-Schiff-base
论文来源:期刊
具体来源:Elsevier Science B.V.
发表时间:2000年

The new NaY zeolite (DMY). whose cages’ size had been expanded, was used as supports for encapsulating the large Schiff-base complexes. The catalysts were used in the aerobic epoxidation of 1-octene. The catalyst showed high activity and selectivity for the substrate and products. These catalysts proved to be more active than other kind of metal ion or supports. The effect of temperature, organic acid or base, and the amount of catalyst was discussed.