作者:ZI-QIANG LEI, XIAN-GEN HAN, YU-LAI HU, RONG-MIN WANG, YUN-PU WANG
关键字:polymer-bound cobalt complexes; catalysts; alkylbenzenes; cobalt complexes;
论文来源:期刊
具体来源:J Appl Polym Sci 75: 1068–1074, 2000
发表时间:2000年
Polymer-bound 2,29-bipyridine cobalt complexes PSBPY-Co, PSBPY-Cobipy,
PSBPY-Co-oxine, and PSBPY-Co-phen (where PSBPY: polystyrene bound-2,29-
bipyridine; bipy: 2,29-bipyridine; phen: 1,10-phenanthroline) were synthesized and
investigated by IR, X-ray photoelectric spectroscopy, thermogravimetry–differential
thermal analysis, inductively coupled plasma atomic emission spectrometry, and elemental analysis. The complexes were found to be catalysts for the oxidation of alkylbenzenes and cyclohexene in the presence of molecular oxygen in the absence of solvent.