A facile one-step synthesis to cross-linked polymeric nanoparticles as highly active and selective catalysts for cycloaddition of CO2 to epoxides
writer:Yubing Xiong, Hong Wang, Rongmin Wang,Yunfeng Yanb Bo Zheng,Yunpu Wang
keywords:Aerobic oxidation; Polymer-bound Schiff base ternary;complexes; Linear aliphatic olefins; Epoxidation
source:期刊
specific source:Chem. Commun., 2010, 46, 3399–3401 | 3399
Issue time:2010年
A very convenient one-step synthesis to cross-linked polymeric nanoparticles by conventional radical copolymerization without the addition of stabilizers or surfactants was explored. Moreover, these nanoparticles exhibited excellent stability, activity and selectivity in the cycloaddition reaction of CO2 to epoxides and
could be separated from the products easily and reused.