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Preparation of polymeric sheet porphyrin complexes and their environmentally benignly catalytic activity
writer:Yu-Feng He , Rong-Min Wang ,Yun-Pu Wang , Chun-Gu Xia
keywords:Polymeric sheet porphyrin; Dioxygen; Environmental benign
source:期刊
specific source:Elsevier Science
Issue time:2002年

The polymeric meso-tetra-(1,5-naphthalene bisulfonyloxo)phenylporphyrin and its complexes (PTNBSOPPM,M =Co, Mn, Fe) have been prepared in the presence of phase-transfer catalyst. Catalyzed by polymeric porphyrin
complexes (PTNBSOPPM), styrene can be aerobic oxidized. The main products come from cleavage of double bond is
in catalytic oxidation of styrene or a-methyl styrene.