writer:ZI-QIANG LEI, XIAN-GEN HAN, YU-LAI HU, RONG-MIN WANG, YUN-PU WANG
keywords:polymer-bound cobalt complexes; catalysts; alkylbenzenes; cobalt complexes;
source:期刊
specific source:J Appl Polym Sci 75: 1068–1074, 2000
Issue time:2000年
Polymer-bound 2,29-bipyridine cobalt complexes PSBPY-Co, PSBPY-Cobipy,
PSBPY-Co-oxine, and PSBPY-Co-phen (where PSBPY: polystyrene bound-2,29-
bipyridine; bipy: 2,29-bipyridine; phen: 1,10-phenanthroline) were synthesized and
investigated by IR, X-ray photoelectric spectroscopy, thermogravimetry–differential
thermal analysis, inductively coupled plasma atomic emission spectrometry, and elemental analysis. The complexes were found to be catalysts for the oxidation of alkylbenzenes and cyclohexene in the presence of molecular oxygen in the absence of solvent.