Preparation of Poly(ionic liquid) Nanoparticles through RAFT/MADIX Polymerization-Induced Self-Assembly
作者:Qi Zhang, Milin Fu, Chengjian Wang, Jianli Wang,Shiping Zhu
关键字:Poly(ionic liquid) Nanoparticles,RAFT/MADIX PISA
论文来源:期刊
具体来源:Polymer Chemistry
发表时间:2017年
We report herein a facile method for hierarchical regulation of the morphology of poly(ionic liquid) (PIL) nanoparticles through RAFT/MADIX aqueous polymerization-induced self-assembly of 3-n-dodecyl-1-vinylimidazolium bromide, by using PEG-xanthate as the macro-CTA. Rigid straight rods were formed over a broad composition range even at low solids, due to the high
incompatibility between the charged PIL block and the neutral PEG block.